Gold as Pollution Tracer in Holocene Sediments of the Doñana National Park, the Largest Biological Reserve in Europe

Abstract

Estuaries are excellent containers for the prehistorical and historical pollution that develops in their river basins. This paper studies the Au contents obtained by inductively coupled plasma spectrometry of two cores extracted from the Do & ntilde;ana National Park (Guadalquivir Estuary, SW Spain). Concentrations of this precious metal have been associated with the different prehistoric and historical stages of exploitation of the Iberian Pyritic Belt. The three detected peaks correspond to the first mining operations in the area around the park, the first systematic Tartessian mining and strong exploitation during the Roman period. Consequently, Au is an appropriate marker of the contamination phases prior to its current extraordinary biological diversity.