Selective sulfoxidation with hydrogen peroxide catalysed by a titanium catalyst

Postigo, LorenaVentura, MariaCuenca, TomásJimenez, GerardoRoyo, Beatriz2025-01-242025-01-242014-08-21L.Postigo; M.Ventura; T.Cuenca; G.Jimenez; B.Royo. Selective sulfoxidation with hydrogen peroxide catalysed by a titanium catalyst Catal. Sci. Technol., 2015,5, 320-3242044-4753 (print)2044-4761 (online)https://hdl.handle.net/10115/62317A moisture-tolerant cyclopentadienyl-silsesquioxane titanium complex efficiently catalyses the selective oxidation of various types of sulfides to either sulfoxides (TOFs up to 32 530 h(-1)) or sulfones with H2O2 (30% in water) under mild conditions.enAlkenesDesulfurizationEfficient EpoxidationMild oxidationOrganic sulfidesSilicaSulfonesSelective sulfoxidation with hydrogen peroxide catalysed by a titanium catalystArticledoi.org/10.1039/C4CY00965Ginfo:eu-repo/semantics/openAccess