Examinando por Autor "Durrant, J.R."

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Towards the improvement of methane production in CO2 photoreduction using Bi2WO6/TiO2 heterostructures
(Elsevier, 2023) Collado, L.; Gómez-Mendoza, M.; García-Tecedor, M.; Oropeza, F.E.; Reynal, A,; Durrant, J.R.; Serrano, D.P.; de la Peña O´Shea, V.A.
Russelite bismuth tungstate (Bi2WO6) has been widely reported for the photocatalytic degradation and mineralization of a myriad of pollutants as well as organic compounds. These materials present perovskite-like structure with hierarchical morphologies, which confers excellent optoelectronic properties as potentials candidates for photocatalytic solar fuels production. Here, we propose the development of Bi2WO6/TiO2 heterojunctions for CO2 photoreduction, as a promising solution to produce fuels, alleviate global warming and tackle fossil fuel shortage. Our results show an improvement of the photocatalytic activity of the heterojunctions compared to the pristine semiconductors. Near Ambient Pressure X-ray Photoelectron Spectroscopy (NAP-XPS) experiments reveals a preferential CO2 adsorption over TiO2. On the other hand, transient absorption spectroscopy measurements show that the charge transfer pathway in Bi2WO6/TiO2 hybrids leads to longer-lived photogenerated carriers in spatially separated redox active sites, which favor the reduction of CO2 into highly electron demanding fuels and chemicals, such as CH4 and C2H6.
Unravelling the effect of charge dynamics at the plasmonic metal/semiconductor interface for CO2 photoreduction
(Nature Publishing Group, 2018) Collado, L.; Reynal, A.; Fresno, F.; Barawi, M.; Escudero, C.; Pérez-Dieste, V.; Coronado, J.M.; Serrano, D.P.; Durrant, J.R.; de la Peña O´Shea, V.A.
Sunlight plays a critical role in the development of emerging sustainable energy conversion and storage technologies. Lightinduced CO2 reduction by artificial photosynthesis is one of the cornerstones to produce renewable fuels and environmentally friendly chemicals. Interface interactions between plasmonic metal nanoparticles and semiconductors exhibit improved photoactivities under a wide range of the solar spectrum. However, the photo-induced charge transfer processes and their influence on photocatalysis with these materials are still under debate, mainly due to the complexity of the involved routes occurring at different timescales. Here, we use a combination of advanced in situ and time-resolved spectroscopies covering different timescales, combined with theoretical calculations, to unravel the overall mechanism of photocatalytic CO2 reduction by Ag/TiO2 catalysts. Our findings provide evidence of the key factors determining the enhancement of photoactivity under ultraviolet and visible irradiation, which have important implications for the design of solar energy conversion materials.