Examinando por Autor "Vohradska, Nikoleta"
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Ítem Controlled photorelease of alkynoic acids and their decarboxylative deprotection for copper-catalyzed azide/alkyne cycloaddition(Royal Society of Chemistry, 2018-05-15) Vohradska, Nikoleta; Sanchez-Carnerero, E. M.; Pastierik, Tomas; Mazal, Ctibor; Klán, PetrA controlled photorelease of alkynoic acids from the meso-methyl BODIPY photoremovable protecting group facilitates their subsequent efficient decarboxylation to give terminal alkynes for a CuI-catalyzed azide/alkyne cycloaddition. The quantum efficiencies of the photochemical step and the kinetics of the click reaction step are reported