Abstract
A controlled photorelease of alkynoic acids from the meso-methyl
BODIPY photoremovable protecting group facilitates their subsequent
efficient decarboxylation to give terminal alkynes for a CuI-catalyzed
azide/alkyne cycloaddition. The quantum efficiencies of the photochemical
step and the kinetics of the click reaction step are reported
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Royal Society of Chemistry
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Support for this work was provided by the Czech Science
Foundation (GA13-25775S). The authors thank Marek Martı´nek
for valuable help with technical issues, and Lucie Ludvı´kova´ for
help in the determination of quantum yields
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Chem. Commun., 2018,54, 5558-5561 BibTex
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