| dc.contributor.author | Honrado, Manuel | |
| dc.contributor.author | Sobrino, Sonia | |
| dc.contributor.author | Fernández-Baeza, Juan | |
| dc.contributor.author | Sánchez-Barba, Luis F. | |
| dc.contributor.author | Garcés, Andrés | |
| dc.contributor.author | Lara-Sánchez, Agustín | |
| dc.contributor.author | Rodríguez, Ana M. | |
| dc.date.accessioned | 2020-12-15T11:22:53Z | |
| dc.date.available | 2020-12-15T11:22:53Z | |
| dc.date.issued | 2019 | |
| dc.identifier.citation | Chem. Commun., 2019,55, 8947-8950 | es |
| dc.identifier.issn | 1364-548X | |
| dc.identifier.uri | http://hdl.handle.net/10115/17339 | |
| dc.description | Preprint | es |
| dc.description.abstract | A novel nucleophilic addition of an organolithium to a ketenimine to prepare an enantiopure NNN-heteroscorpionate ligand is described. We verified its potential utility as a valuable scaffold for chirality induction through the preparation of enantiopure zinc complexes, which behave as highly efficient initiators to produce highly-enriched isotactic poly(lactide)s (Pi up to 0.88). | es |
| dc.language.iso | eng | es |
| dc.publisher | Royal Society of Chemistry | es |
| dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
| dc.subject | Química | es |
| dc.subject | Zinc | es |
| dc.subject | enantiopure ligand | es |
| dc.subject | isotactic polymer | es |
| dc.subject | lactide | es |
| dc.subject | PLA | es |
| dc.title | Synthesis of an Enantiopure Scorpionate Ligand by a Nucleophilic Addition to a Ketenimine and a Zinc Initiator for the Isoselective ROP of rac-Lactide | es |
| dc.type | info:eu-repo/semantics/preprint | es |
| dc.identifier.doi | 10.1039/C9CC04716F | es |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
| dc.subject.unesco | 23 Química | es |
Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivatives 4.0 Internacional