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Thermomechanically Robust Ceramic/Polymer Nanocomposites Modified with Ionic Liquid for Hybrid Polymer Electrolyte Applications

dc.contributor.authorBosque, Antonio del
dc.contributor.authorMuñoz, Bianca K.
dc.contributor.authorSánchez, María
dc.contributor.authorUreña, Alejandro
dc.identifier.citationAntonio del Bosque, Bianca K. Muñoz, María Sánchez, and Alejandro Ureña ACS Applied Energy Materials 2022 5 (4), 4247-4258 DOI: 10.1021/acsaem.1c03836es
dc.descriptionCopyright © 2022 The Authors. Published by American Chemical Society. This publication is licensed under CC-BY
dc.description.abstractThe development of hybrid electrolytes (HEs) that allows high mechanical properties and high ionic conductivity is a key in the smart mobility progress. In this article, various solid polymer electrolytes (SPEs) based on a blend of epoxy resins, ionic liquid, and titania or alumina nanoparticles have been manufactured and their electrochemical and thermomechanical performances have been evaluated. The combination of SPE components providing the highest properties was studied, having a significant influence on the type of nanoparticles and their dispersion. The electrolyte with the best combination of properties was L65P35(ILE)Al2, which showed Tg = 83 °C and E′ at 30 °C = 1.2 GPa as thermomechanical properties, and σ0 = 7 × 10–4 S/cm, σ1 = 1.6 × 10–6 S/cm, and Csp = 5.6 × 10–5 F/g at room temperature, as electrochemical properties. Moreover, the optimized electrolyte followed the Arrhenius ion transport model (Ea = 24.7 kJ/mol). These results would be promising for use as hybrid electrolyte in structural
dc.rightsAtribución 4.0 Internacional*
dc.subjectIonic conductivityes
dc.subjectOrganic polymerses
dc.titleThermomechanically Robust Ceramic/Polymer Nanocomposites Modified with Ionic Liquid for Hybrid Polymer Electrolyte Applicationses

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Atribución 4.0 InternacionalExcept where otherwise noted, this item's license is described as Atribución 4.0 Internacional