Show simple item record

SYNTHESIS OF HIERARCHICAL ZSM-5 BY SILANIZATION AND ALKOXYLATION OF PROTOZEOLITIC UNITS

dc.contributor.authorSerrano, D.P.
dc.contributor.authorAguado, J.
dc.contributor.authorEscola, J.M.
dc.contributor.authorPeral, Ángel
dc.contributor.authorMorales, Gabriel
dc.contributor.authorAbella, E.
dc.date.accessioned2011-10-24T09:50:22Z
dc.date.available2011-10-24T09:50:22Z
dc.date.issued2011
dc.identifier.citationCatalysis Today, 168 (2011) 86-95es
dc.identifier.urihttp://hdl.handle.net/10115/5673
dc.description.abstractHierarchical ZSM-5 zeolite has been synthesized by means of a method involving a precrystallization stage to form the protozeolitic units, the addition and subsequent grafting of both silanization and alkoxylation agents, and a final hydrothermal crystallization. The influence of the alkoxylation with different alcohols (methanol, ethanol, 2-propanol and n-butanol) on the properties of the final hierarchical ZSM-5 samples has been investigated. In every case, the alcohol addition increased the incorporation of the seed silanization agent as it decreases the gel viscosity. In addition, the presence of alcohols deeply affects the physicochemical properties of the final materials. The samples prepared with 2-propanol and methanol were highly crystalline and presented improved textural properties with regard to the reference h-ZSM-5 and n-ZSM-5. In contrast, the samples obtained with ethanol and n-butanol were partially and totally X-ray amorphous, respectively. 1H and 13C-CP solid state MAS NMR spectra proved the alkoxylation of the external surface of the protozeolitic units. Catalytic cracking of LDPE pointed out the higher TOF values obtained over the hierarchical samples prepared with methanol and 2-propanol due to a right combination of accessibility and crystallinity in these materials. The differences observed among the samples prepared with alcohols were ascribed to the strong interaction produced between the silanization agent and the linear alcohols on the surface of the protozeolitic nanounits, which form a very stable protective layer, hindering their aggregation and subsequent crystallization.es
dc.language.isoenes
dc.publisherELSEVIERes
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subjectMedio Ambientees
dc.subjectDiseño de nuevos catalizadoreses
dc.titleSYNTHESIS OF HIERARCHICAL ZSM-5 BY SILANIZATION AND ALKOXYLATION OF PROTOZEOLITIC UNITSes
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doi10.1016/j.cattod.2010.12.040es
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.subject.unesco23 Químicaes
dc.description.departamentoTecnología Química y Energética


Files in this item

This item appears in the following Collection(s)

Show simple item record

Atribución-NoComercial-SinDerivadas 3.0 EspañaExcept where otherwise noted, this item's license is described as Atribución-NoComercial-SinDerivadas 3.0 España