Selective sulfoxidation with hydrogen peroxide catalysed by a titanium catalyst

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C4CY00965G.pdf (685.37 KB)

Fecha

2014-08-21

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Título del volumen

Editor

Royal Society of Chemistry

URI

https://hdl.handle.net/10115/62317

DOI

https://doi.org/doi.org/10.1039/C4CY00965G

Resumen

A moisture-tolerant cyclopentadienyl-silsesquioxane titanium complex efficiently catalyses the selective oxidation of various types of sulfides to either sulfoxides (TOFs up to 32 530 h(-1)) or sulfones with H2O2 (30% in water) under mild conditions.

Descripción

Palabras clave

Alkenes , Desulfurization , Efficient Epoxidation , Mild oxidation , Organic sulfides , Silica , Sulfones

Citación

L.Postigo; M.Ventura; T.Cuenca; G.Jimenez; B.Royo. Selective sulfoxidation with hydrogen peroxide catalysed by a titanium catalyst Catal. Sci. Technol., 2015,5, 320-324

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