Polymerization at High Pressure of Dimethyl-Acetylene: Raman Microscopy, Vibrational
dc.contributor.author | Pérez Tejedor, francisco JAvier | |
dc.contributor.author | Rodríguez Montoro, Óscar | |
dc.contributor.author | Rodríguez Jiménez, Olga | |
dc.contributor.author | García Baonza, Valentín | |
dc.contributor.author | Núñez Delgado, Javier | |
dc.date.accessioned | 2024-07-15T07:11:25Z | |
dc.date.available | 2024-07-15T07:11:25Z | |
dc.date.issued | 2002-01-01 | |
dc.description.abstract | We have measured the Raman spectrum of the dimethyl acetylene in the pressure range 0,1-62 kbar at room temperature. We have found three induced phase transitions at 0.1, 9 and 26 kbar. We have also found a massive polymerization reaction in this system which begins around 35 kbar. A force field treatment has been performed as a function of pressure, which allows analyzing the behaviour of the force constants with pressure for the dimethyl-acetylene. | es |
dc.identifier.citation | Pérez Tejedor, F. J., Montoro, O. R., Rodríguez-Jiménez, O., Baonza, V. G., & Núñez Delgado, J. (2002). Polymerization at High Pressure of Dimethyl Acetylene: Raman Microscopy, Vibrational Analysis, Calculation of Force Constants and Internal Coordinates. Defect and Diffusion Forum, 208–209, 121–124. https://doi.org/10.4028/www.scientific.net/ddf.208-209.121 | es |
dc.identifier.doi | 10.4028/www.scientific.net/ddf.208-209.121 | es |
dc.identifier.issn | 1662-950 | |
dc.identifier.uri | https://hdl.handle.net/10115/37960 | |
dc.language.iso | eng | es |
dc.publisher | Trans Tech Publications | es |
dc.rights.accessRights | info:eu-repo/semantics/closedAccess | es |
dc.subject | Dimethyl acetylene | es |
dc.subject | High pressure | es |
dc.subject | Phase transition | es |
dc.subject | Raman Spectroscopy | es |
dc.title | Polymerization at High Pressure of Dimethyl-Acetylene: Raman Microscopy, Vibrational | es |
dc.type | info:eu-repo/semantics/article | es |
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