Abstract

Titanium complexes bearing an unprecedented tridentate cyclopentadienyl−silsesquioxanate ligand provide a new class of efficient and selective catalysts for epoxidation of olefins with aqueous hydrogen peroxide under homogeneous conditions.
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American Chemical Society

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En este artículo se realiza la epoxidación de alkenos por primera vez en medio acuoso con complejos de titanio-silicio

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Cyclopentadienyl–Silsesquioxane Titanium Complexes: Highly Active Catalysts for Epoxidation of Alkenes with Aqueous Hydrogen Peroxide María Ventura, Marta E. G. Mosquera, Tomás Cuenca, Beatriz Royo, and Gerardo Jiménez Inorganic Chemistry 2012 51 (11), 6345-6349

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