SYNTHESIS OF HIERARCHICAL TS-1 ZEOLITE FROM SILANIZED SEEDS

dc.contributor.authorSerrano, D.P.
dc.contributor.authorSanz, Raúl
dc.contributor.authorPizarro, Patricia
dc.contributor.authorMoreno, Inés
dc.date.accessioned2011-02-07T15:26:28Z
dc.date.available2011-02-07T15:26:28Z
dc.date.issued2010
dc.description.abstractHierarchical TS-1 zeolites with a bimodal pore architecture, consisting of the typical MFI micropores and an additional mesoporosity, have been synthesized by grafting an organosilane compound to the zeolitic seeds previously prepared from two different raw materials: a liquid gel and an amorphous SiO2-TiO2 xerogel. These hierarchical TS-1 zeolites show an excellent catalytic behavior in olefin epoxidation reactions employing organic hydroperoxides as oxidants due to the presence of the secondary mesoporosity, which makes possible the access and interaction of bulky molecules with the Ti active siteses
dc.description.departamentoTecnología Química y Energética
dc.identifier.citationTopics in Catalysis: Volume 53, Numbers 19-20, pag. 1319-1329.es
dc.identifier.doi10.1007/s11244-010-9590-9es
dc.identifier.urihttp://hdl.handle.net/10115/4807
dc.language.isoenes
dc.publisherELSEVIERes
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subjectQuímicaes
dc.subject.unesco23 Químicaes
dc.subject.unesco2391 Química Ambientales
dc.titleSYNTHESIS OF HIERARCHICAL TS-1 ZEOLITE FROM SILANIZED SEEDSes
dc.typeinfo:eu-repo/semantics/articlees

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