Synthesis and electrochemical characterization of donor-acceptor phenylazomethine dendrimers
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2005-12
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The synthesis of the first donor-acceptor phenylazomethine dendrimers (4 and 5) is described. A convergent method is used via the condensation of aromatic ketones with an appropriately functionalized tri(aminophenyl)-s-triazine promoted by titanium (IV) chloride. Cyclic voltammetry investigations show a donor-acceptor behaviour due to the presence of the electron acceptor s-triazine core and the donor ability of the conjugated peripheral butoxybenzene units.
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Versión final: Tetrahedron Letters, Volume 46, Issue 51, 19 December 2005, Pages 8861-8864
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