dc.contributor.author | van Grieken, R. | |
dc.contributor.author | Escola, J. M. | |
dc.contributor.author | Moreno, J. | |
dc.contributor.author | Rodríguez, R. | |
dc.date.accessioned | 2010-04-19T15:07:59Z | |
dc.date.available | 2010-04-19T15:07:59Z | |
dc.date.issued | 2009 | |
dc.identifier.citation | Chemical Engineering Journal 155 (2009) 442-450 | es |
dc.identifier.uri | http://hdl.handle.net/10115/3768 | |
dc.description.abstract | M-SBA-15 materials (M = Al, B, Cr, Fe) were prepared by different direct synthesis methods, characterized and tested catalytically in the 1-hexene oligomerization reaction at 125ºC. Al-SBA-15 were synthesized within the range Si/Al=12-86 using aluminium isopropoxide as aluminium source. 27Al MAS NMR spectra point out that the three Al-SBA-15 samples contain more tetrahedral aluminium than octahedral and the ratio tetrahedral / octahedral diminished with increasing aluminium contents. B-SBA-15 was prepared with a Si/B=51-106 using two direct synthesis methods (sol-gel and hydrothermal) and three different boron sources (solid boric acid, aqueous boric acid and boron isopropoxide). The best results in terms of boron incorporation (Si/B = 51) were achieved with solid boric acid and the sol-gel method, although a lower degree of mesoscopic ordering was obtained compared to the hydrothermal procedure. 11B MAS NMR showed that trigonal boron is the principal coordination state obtained after calcination. Cr-SBA-15 was also achieved by direct synthesis method at different pH (1.5, 3, 5) but the incorporation degree was low, at best Si/Cr = 240 at pH = 5. UV-vis spectroscopy indicated that all Cr species were Cr6+ formed during the calcination step. Oligomerization of 1-hexene at 125ºC showed that the highest conversion (~ 30%) was attained over Al-SBA-15 (Si/Al=30) although Cr-SBA-15 material exhibited close conversion (21%) despite its low heteroatom content (Si/Cr = 240). Dimers were the major products over Al-SBA-15, Cr-SBA-15 and Fe-SBA-15 catalysts (selectivity ¿ 40%) while strikingly, sol gel B-SBA-15 lead mostly to heavy oligomers (> 60%), with less than 10 % of dimers. | es |
dc.language.iso | en | es |
dc.publisher | ELSEVIER | es |
dc.rights | Atribución-NoComercial-SinDerivadas 3.0 España | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es/ | * |
dc.subject | Combustibles Fósiles | es |
dc.title | Direct synthesis of mesoporous M-SBA-15 (M = Al, Fe, B, Cr) and application to 1-hexene oligomerization | es |
dc.type | info:eu-repo/semantics/article | es |
dc.identifier.doi | 10.1016/j.cej.2009.07.016 | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.subject.unesco | 23 Química | es |
dc.description.departamento | Tecnología Química y Ambiental | |