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Polymerization at High Pressure of Dimethyl-Acetylene: Raman Microscopy, Vibrational

dc.contributor.authorPérez Tejedor, francisco JAvier
dc.contributor.authorRodríguez Montoro, Óscar
dc.contributor.authorRodríguez Jiménez, Olga
dc.contributor.authorGarcía Baonza, Valentín
dc.contributor.authorNúñez Delgado, Javier
dc.date.accessioned2024-07-15T07:11:25Z
dc.date.available2024-07-15T07:11:25Z
dc.date.issued2002-01-01
dc.identifier.citationPérez Tejedor, F. J., Montoro, O. R., Rodríguez-Jiménez, O., Baonza, V. G., & Núñez Delgado, J. (2002). Polymerization at High Pressure of Dimethyl Acetylene: Raman Microscopy, Vibrational Analysis, Calculation of Force Constants and Internal Coordinates. Defect and Diffusion Forum, 208–209, 121–124. https://doi.org/10.4028/www.scientific.net/ddf.208-209.121es
dc.identifier.issn1662-950
dc.identifier.urihttps://hdl.handle.net/10115/37960
dc.description.abstractWe have measured the Raman spectrum of the dimethyl acetylene in the pressure range 0,1-62 kbar at room temperature. We have found three induced phase transitions at 0.1, 9 and 26 kbar. We have also found a massive polymerization reaction in this system which begins around 35 kbar. A force field treatment has been performed as a function of pressure, which allows analyzing the behaviour of the force constants with pressure for the dimethyl-acetylene.es
dc.language.isoenges
dc.publisherTrans Tech Publicationses
dc.subjectDimethyl acetylenees
dc.subjectHigh pressurees
dc.subjectPhase transitiones
dc.subjectRaman Spectroscopyes
dc.titlePolymerization at High Pressure of Dimethyl-Acetylene: Raman Microscopy, Vibrationales
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doi10.4028/www.scientific.net/ddf.208-209.121es
dc.rights.accessRightsinfo:eu-repo/semantics/closedAccesses


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